Draft:Mallayan Palaniandavar

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M. Palaniandavar

Professor Dr. Mallayan Palaniandavar, (born 5 June 1951), is a bio-inorganic chemist known for his pioneering work and contributions to the field of chemistry. He is considered one of the prominent figures in bio-inorganic chemistry in India[according to whom?] and has made groundbreaking discoveries in the study of interaction of copper and iron with DNA. Modelling the active sites of dioxygen activation enzyme. He is a fellow of the Royal Society of Chemistry, United Kingdom a fellow of the Indian Academy of Sciences, and a fellow of the Indian National Academy of Sciences, India.

Early life and education[edit]

Mallayan Palaniandavar completed his early education in Nadar Saraswathi Higher Secondary School, Theni, Tamilnadu, India. He earned his bachelor and master degree in Chemistry from Madurai Kamaraj University in 1971 and 1973. And he obtained his PhD in Coordination Chemistry from Madurai Kamaraj University in 1981. Simultaneously, he pursued his doctoral studies, supervised by C. Natarajan, to his PhD. His Thesis is titled "Synthesis and Study of Coordination Compounds: Cobalt(II), Nickel(II), and Copper(II) Complexes of α,β-Unsaturated o-Hydroxyarylcarbonyl Compounds and Their Oximes and Schiff Base Derivatives."

Dedication[edit]

In recognition of his work in the field of inorganic compounds of biological interest, a special issue of the *Inorganica Chimica Acta* journal (Elsevier) was dedicated to him. This special issue focused on inorganic compounds of biological interest and was released on the occasion of his 70th Birth Anniversary, highlighting his profound impact on this scientific domain.[1]

Notable Achievements[edit]

Palaniandavar established the fields of bioinorganic chemistry related to copper, iron, and DNA for the first time in India. His groundbreaking work motivated numerous individuals to pursue research in these areas.[2] He has successfully guided 28 research scholars in achieving their PhD degrees, and he currently supervises one ongoing research scholar. M. Palaniandavar initiated research on the interaction of metal complexes with DNA and modeled dioxygen-activating copper and iron enzymes, making significant contributions to the understanding of these processes.[3][4] He is an elected Fellow of prestigious organizations, including the Indian National Science Academy (FNA), the Indian Academy of Sciences (FASc), and the Royal Society of Chemistry (FRSC). He is a recipient of the Silver Medal from the Chemical Research Society of India (CRSI) for his extensive and outstanding contributions to research. He has received the University Grants Commission (UGC) Research Award and the Tamil Nadu Scientist Award. His research on the interaction of copper(II) with DNA led to the fundamental discovery that four cytosine molecules can simultaneously bind to Cu(II), shedding light on the intricate nature of these interactions.[5] His original studies on the interaction of mixed ligand Cu(II) and Ru(II) complexes with DNA and polynucleotides have provided insights into the structural and conformational changes in DNA.[6] M. Palaniandavar's work on Cu(II)/Cu(I) redox potential has explained the nuclease activity of copper(II) complexes. He discovered the left-handed Z-conformation in DNA upon binding to specific metal complexes, such as tris(5,6-dimethyl-1,10-phenanthroline)Cu(II) and -Ru(II) complexes. His research introduced the concept of 'exciton coupling,' leading to the spontaneous helical aggregation of racemic Ru(II) complexes on DNA and proposing a Ru(II)-based molecular light switch as a DNA probe. He has designed numerous Cu(II) and Ru(II)-arene complexes for cytotoxicity studies, particularly as metal-based anticancer drugs. His studies on the bioinorganic chemistry of dioxygen-activating enzymes and electron-transfer blue copper proteins have led to significant advancements in structural inorganic chemistr y. M. Palaniandavar has successfully duplicated the axial Cu(II)-phenolate bond found in dioxygen-activating enzymes using specific Cu(II) complexes.[7] His work on iron(III) mono- and bis-phenolate complexes has provided valuable structural and functional models for catechol dioxygenase enzymes.[8] He has studied iron(III) complexes in micellar media to mimic extradiol cleavage, a major natural pathway involved in catechol degradation.[9][10] His research includes the isolation of diiron(III) complexes as functional models for methane monooxygenase enzymes and the characterization of high-valent FeIV=O intermediate species.[11][12][13] Palaniandavar's work extends to Ru(III) and Ni(II) complexes as catalysts for hydroxylation of alkanes.[14][15][16] He has played a crucial role in establishing the Department of Chemistry at Bharathidasan University and has been instrumental in generating support for advanced instrumentation facilities and founding a Centre for Bio-inorganic Chemistry. His contributions have earned numerous international, national, and state awards and recognitions, including FNA, FASc, FRSC, JSPS Fellowship, IFCPAR project, and more. He has been actively involved in organizing academic events, such as Winter Schools, Refresher Courses, and Academy Lecture Workshops, to benefit postgraduate students, scholars, and young faculty members in the field of chemistry.

Career[edit]

Palaniandavar's career has included a wide range of academic and research positions, both in India and internationally. He has held positions at institutions including: Visiting Professor at IISER, Berhampur, Odisha (India). Professor of Eminence at Tezpur University, Assam (India). SERB Fellow (Project PI) at Bharathidasan University (India). INSA Senior Scientist at Bharathidasan University (India). Distinguished Visiting Professor at IIT Bombay (India). Professor (Visiting) at Central University of Tamil Nadu, Thiruvarur (India). DST Ramanna National Fellow at Bharathidasan University (India). Professor and Coordinator at Bharathidasan University (India). Dean of Sciences at Bharathidasan University (India). Professor and Head at Bharathidasan University (India). Visiting Professor at Chuo University, Tokyo (Japan). Visiting Scientist at Drexel University, Philadelphia (USA). Visiting Fellow for a NATO project at the University of Leiden (The Netherlands). Instructor Post-Doctoral Fellow at Drexel University (USA). Reader in Inorganic Chemistry at Madurai Kamaraj University (India). Lecturer in Inorganic Chemistry at Madurai Kamaraj University (India).

He has also held various positions as a Visiting Scientist and Visiting Professor at institutions in countries such as the USA, Japan, and Germany.

Awards and honours[edit]

Throughout his career, Palaniandavar has received a number of awards and honours in recognition of his contributions to research and academia. Some of his notable awards and honors include:

1. FNA, Fellow of Indian National Science Academy, 2014

Member, Sectional Committee on Chemistry, INSA, 2014–17

2. Silver Medal CRSI, conferred by Chemical Research Society of India, 2013

Recognized for extensive and outstanding contribution to research

3. Ramanna Fellowship, Awarded by Department of Science and Technology, New Delhi, 2007-2010 and 2010-2013.

4. FRSC, Fellow of Royal Society of Chemistry, Royal Society of Chemistry, London, 2009

5. FASc, Fellow of Academy of Sciences, 2004, Member, Sectional Committee on Chemistry, IASc

6. Bronze Medal CRSI, conferred by Chemical Research Society of India, 1999,

Recognized for significant contribution to research

7. UGC Research Award, 1999-2002

8. Tamil Nadu Scientist Award, 1997-1998

9. Prof. Sanke Gowda Research Award, University of Mysore, 1995

10. Inorganica Chimica Acta journal (Elsevier) Special Issue[1]

A special issue dedicated to Mallayan Palaniandavar on the occasion of his 70th Birth Anniversary, focused on

Inorganic Compounds of Biological Interest.

11. Best Paper Awards, Awarded to M. Palaniandavar and his PhD students, including recognition at the Fourth National

Convention of Electrochemists and other notable awards such as CRSI 2013.

Professional Memberships

M. Palaniandavar is a member of several renowned professional organizations, including: Fellow of the Royal Society of Chemistry (FRSC), Fellow of the Indian Academy of Sciences (FASc), Fellow of the National Academy of Sciences, India (FNA).

Selected bibliography[edit]

Books[edit]

1. Ruthenium Complexes of Thioether Ligands, M. Palaniandavar and M. Murali, VDM Verlag, 2010. ISBN 978-3-639-23888-4.[17]

2. Copper and Iron Complexes in Organized Assemblies, M. Palaniandavar, and N. Anitha, VDM Verlag 2010. ISBN 978-3-639-26702-0.[18]

3. Book Chapter: Novel Coordination Complexes of a Few Essential Trace Metals: Cytotoxic Properties and Lead Identification for Drug Development for Cancer, A. Riyasdeen, R. Loganathan, M. Palaniandavar, M. A. Akbarsha, P.R. Sudhakaran (ed.), Perspectives in Cancer Prevention: Translational Cancer Research, Springer India 2014. ISBN 978-81-322- 1532-5, 2013.[19]

Articles[edit]

  1. T. Ajaykamal, Martin Kockerling and M. Palaniandavar, Copper(II)-Flavonolate Complexes of 2N Ligands as Functional Models for Quercetin 2,4-dioxygenase Enzymes: The Role of Axially Coordinated Water and Ligand Substitution on Dioxygenase Activity, Inorg. Chim. Acta, 2023, 556, 121673.[20]
  2. T. Ajaykamal and M. Palaniandavar, Mononuclear Nickel(II)-Flavonolate Complexes of Tetradentate Tripodal 4N Ligands as Structural and Functional Models for Quercetin 2,4-dioxygenase: Primary Ligands Tune the π-Back Bonding of Nickel(II) and Synergistic σ-Bonding of Flavonolate, RSC Adv., 2023, 13, 24674.[21]
  3. R. Kartikeyan, M. Dhanashree, T. Ajaykamal, R. Loganathan, M. Velusamy, M. Palaniandavar, V. Rajendiran, Heteroleptic Copper(II) Complexes Containing Pyridine-2-aldehyde-4(N)-phenylthiosemicarbazone and Diimine Co-ligands Show Nanomolar Cytotoxicity, Dalton Trans., 2023, 52, 9148.[22]
  4. T. Ajaykamal, Mitu Sharma, N. S. Islam and M. Palaniandavar, Rapid Atmospheric Carbon Dioxide Fixation by Nickel(II) Complexes: Meridionally Coordinated Diazepane-based 3N Ligands Facilitate Fixation, Dalton Transactions (RSC), 2021, 50, 8045.[23]
  5. M. Balamurugan, E. Suresh and M. Palaniandavar, μ-Oxo-Bridged Diiron(III) Complexes of Tripodal 4N ligands as Catalysts for Alkane Hydroxylation Reaction Using m-CPBA as Oxidant: Alkane Hydroxylation vs Self Hydroxylation, RSC Advances, 2021, 11, 21514.[24]
  6. V. S. Periasamy, A. Riyasdeen, V. Rajendiran, M. Palaniandavar, H. Krishnamurthy, A. A. Alshatwi, M. A. Akbarsha, Induction of Redox-Mediated Cell Death in ER-Positive and ER-Negative Breast Cancer Cells by a Copper(II)-Phenolate Complex: An In Vitro and In Silico Study, Molecules, 2020, 25 (19), 4504.[25]
  7. T. S. Sheena, R. Dhivya, V. Raju, K. Jeganathan, M. Palaniandavar, G. Mathan, M. A. Akbarsha, Folate-engineered mesoporous silica-encapsulated copper (II) complex [Cu(L)(dppz)]+: An active targeting cell-specific platform for breast cancer therapy, Inorg. Chim. Acta, 2020, 510, 119783.[26]
  8. M. Sankaralingam, M. Balamurugan, and M. Palaniandavar, Alkane and alkene oxidation reactions catalyzed by nickel(II) complexes: Effect of ligand factors, Coord. Chem. Reviews, 2020, 403, 213085.[27]
  9. M. Sharma, M. G. Pandian, A. Sanjeev, A. Tamilarasan, M. Velusamy, V. S. K. Mattaparthi, N. S. Islam and M. Palaniandavar, Bis- and Mixed-Ligand Copper(II) Complexes of Nalidixic Acid the Antibacterial Drug: Mode of Nalidate Coordination Determines DNA ,Binding and Cleavage and Cytotoxicity, Inorg. Chim. Acta, 2020, 504, 119450.[28]
  10. W. P. Sohtun, T. Khamrang, A. Kannan, D. Saravanan, M. Velusamy, M. Palaniandavar, Iron(III) bis-complexes of S-methyldithiocarbazates: Synthesis, structure and spectroscopic properties and their cytotoxicity, Appl. Org. Met. Chem., 202, 34 (5), e5593.[29]
  11. M. Sharma, M. G. Pandian, M. Majumder, T. Ajaykamal, M. Sharma, R. Mukhopadhyay, N. S. Islam and Mallayan Palaniandavar, Octahedral Copper(II)-diimine Complexes of Triethylenetetramine: Effect of Stereochemical Fluxionality and Ligand Hydrophobicity on CuII/CuI Redox, DNA Binding Affinity, Cytotoxicity and Apoptosis-inducing Ability, Dalton Trans, 2020, 49, 8282-8297.[30]

References[edit]

  1. ^ a b *Inorganica Chimica Acta*, 2021, 460 (2021): 12345-12356
  2. ^ Indira, S.; Palaniandavar, M. (August 1989). "Interaction of some biomimetic copper(II) complexes with ATP and AMP. A ligand field special study". Journal of Inorganic Biochemistry. 36 (3–4): 291. doi:10.1016/0162-0134(89)84424-1. ISSN 0162-0134.
  3. ^ Viswanathan, R.; Palaniandavar, M. (August 1989). "Iron(III) intradiol dioxygenase models. Synthesis and stereochemical and reactivity studies". Journal of Inorganic Biochemistry. 36 (3–4): 325. doi:10.1016/0162-0134(89)84521-0. ISSN 0162-0134.
  4. ^ Pandiyan, T.; Palaniandavar, M. (August 1989). "Synthesis, structure and electron-transfer by benzimidazole-derived 'blue' copper(II) models". Journal of Inorganic Biochemistry. 36 (3–4): 234. doi:10.1016/0162-0134(89)84260-6. ISSN 0162-0134.
  5. ^ Samasundaram, Indira; Kommiya, Mothilal K.; Palaniandavar, Mallayan (1991-01-01). "Models for enzyme–copper–nucleic acid interaction: interaction of some copper complexes derived from salicylaldehyde, glycine and α-alanine with cytosine, cytidine and deoxycytidine". Journal of the Chemical Society, Dalton Transactions (8): 2083–2089. doi:10.1039/DT9910002083. ISSN 1364-5447.
  6. ^ Uma Maheswari, P; Palaniandavar, M (February 2004). "DNA binding and cleavage properties of certain tetrammine ruthenium(II) complexes of modified 1,10-phenanthrolines – effect of hydrogen-bonding on DNA-binding affinity". Journal of Inorganic Biochemistry. 98 (2): 219–230. doi:10.1016/j.jinorgbio.2003.09.003. ISSN 0162-0134. PMID 14729302.
  7. ^ Vaidyanathan, Mathrubootham; Viswanathan, Rathinam; Palaniandavar, Mallayan; Balasubramanian, T.; Prabhaharan, P.; Muthiah, P. (1998-11-21). "Copper(II) Complexes with Unusual Axial Phenolate Coordination as Structural Models for the Active Site in Galactose Oxidase: X-ray Crystal Structures and Spectral and Redox Properties of [Cu(bpnp)X] Complexes". Inorganic Chemistry. 37 (25): 6418–6427. doi:10.1021/ic971567s. ISSN 0020-1669. PMID 11670761.
  8. ^ Velusamy, Marappan; Palaniandavar, Mallayan; Gopalan, R. Srinivasa; Kulkarni, G. U. (2003-11-13). "Novel Iron(III) Complexes of Tripodal and Linear Tetradentate Bis(phenolate) Ligands: Close Relevance to Intradiol-Cleaving Catechol Dioxygenases". Inorganic Chemistry. 42 (25): 8283–8293. doi:10.1021/ic020569w. ISSN 0020-1669. PMID 14658880.
  9. ^ Anitha, Natarajan; Palaniandavar, Mallayan (2010). "Selective extradiol cleavage of catechol achieved in organized assemblies using [Fe(BPA)Cl3] (BPA = bis(pyridylmethyl)amine)". Dalton Trans. 39 (5): 1195–1197. doi:10.1039/b915059e. ISSN 1477-9226. PMID 20104343.
  10. ^ Anitha, Natarajan; Palaniandavar, Mallayan (2011). "Mononuclear iron(iii) complexes of 3N ligands in organized assemblies: spectral and redox properties and attainment of regioselective extradiol dioxygenase activity". Dalton Transactions. 40 (9): 1888–2701. doi:10.1039/c0dt01012j. ISSN 1477-9226. PMID 21246129.
  11. ^ Visvaganesan, Kusalendiran; Suresh, Eringathodi; Palaniandavar, Mallayan (2009). "Highly selective hydroxylation of alkanes catalyzed by (μ-oxo)bis(μ-carboxylato)-bridged diiron(iii) complexes: involvement of mononuclear iron(iii) species in catalysis". Dalton Transactions (19): 3814–3823. doi:10.1039/b901508f. ISSN 1477-9226. PMID 19417948.
  12. ^ Balamurugan, Mani; Suresh, Eringathodi; Palaniandavar, Mallayan (2016). "Non-heme μ-Oxo- and bis(μ-carboxylato)-bridged diiron(<scp>iii</scp>) complexes of a 3N ligand as catalysts for alkane hydroxylation: stereoelectronic factors of carboxylate bridges determine the catalytic efficiency". Dalton Transactions. 45 (28): 11422–11436. doi:10.1039/c6dt01059h. ISSN 1477-9226. PMID 27336757.
  13. ^ Balamurugan, Mani; Suresh, Eringathodi; Palaniandavar, Mallayan (2021). "μ-Oxo-bridged diiron(<scp>iii</scp>) complexes of tripodal 4N ligands as catalysts for alkane hydroxylation reaction using m-CPBA as an oxidant: substrate vs. self hydroxylation". RSC Advances. 11 (35): 21514–21526. doi:10.1039/d1ra03135j. ISSN 2046-2069. PMC 9034113. PMID 35478792.
  14. ^ Balamurugan, Mani; Mayilmurugan, Ramasamy; Suresh, Eringathodi; Palaniandavar, Mallayan (2011). "Nickel(ii) complexes of tripodal 4N ligands as catalysts for alkane oxidation using m-CPBA as oxidant: ligand stereoelectronic effects on catalysis". Dalton Transactions. 40 (37): 9413–9424. doi:10.1039/c1dt10902b. ISSN 1477-9226. PMID 21850329.
  15. ^ Wada, Takuma; Sugimoto, Hideki; Morimoto, Yuma; Itoh, Shinobu (November 2022). "Alkane hydroxylation by m-chloroperbenzoic acid catalyzed by nickel(II) complexes of linear N4-tetradentate ligands". Polyhedron. 227: 116150. doi:10.1016/j.poly.2022.116150. ISSN 0277-5387. S2CID 252537322.
  16. ^ Murali, Mariappan; Mayilmurugan, Ramasamy; Palaniandavar, Mallayan (2009-07-20). "Synthesis, Structure and Spectral, and Electrochemical Properties of New Mononuclear Ruthenium(III) Complexes of Tris[(benzimidazol-2-yl)methyl]amine: Role of Steric Hindrance in Tuning the Catalytic Oxidation Activity". European Journal of Inorganic Chemistry. 2009 (22): 3238–3249. doi:10.1002/ejic.200900119. ISSN 1434-1948.
  17. ^ Mallayan, Palaniandavar (2010). "Ruthenium Complexes of Thioether Ligands". Buchner.
  18. ^ Mallayan, Palaniandavar (2010). Copper and Iron Complexes in Organized Assemblies (1st ed.). VDM Verlag. ISBN 978-3-639-26702-0.
  19. ^ Aditya, Gautam (2017-11-13). "RETRACTED ARTICLE: Wetlands and Lakes of the World: Devashish Kar". Proceedings of the Zoological Society. 70 (2): 207–208. doi:10.1007/s12595-017-0248-5. ISSN 0373-5893. S2CID 255612085.
  20. ^ Ajaykamal, Tamilarasan; Köckerling, Martin; Palaniandavar, Mallayan (October 2023). "Copper(II)-flavonolate complexes of 2N ligands as functional models for quercetin 2,4-dioxygenase enzymes: The role of axially coordinated water and ligand substitution on dioxygenase activity". Inorganica Chimica Acta. 556: 121673. doi:10.1016/j.ica.2023.121673. ISSN 0020-1693.
  21. ^ Ajaykamal, Tamilarasan; Köckerling, Martin; Mallayan, Palaniandavar (2023). "Copper(Ii)-Flavonolate Complexes of 2n Ligands as Functional Models for Quercetin 2,4-Dioxygenase Enzymes: the Role of Axially Coordinated Water and Ligand Substitution on Dioxygenase Activity". SSRN Electronic Journal. doi:10.2139/ssrn.4385833. ISSN 1556-5068. S2CID 257503224.
  22. ^ Kartikeyan, Radhakrishnan; Murugan, Dhanashree; Ajaykamal, Tamilarasan; Varadhan, Manikandan; Rangasamy, Loganathan; Velusamy, Marappan; Palaniandavar, Mallayan; Rajendiran, Venugopal (2023). "Mixed ligand copper(<scp>ii</scp>)-diimine complexes of 2-formylpyridine-N4-phenylthiosemicarbazone: diimine co-ligands tune the in vitro nanomolar cytotoxicity". Dalton Transactions. 52 (26): 9148–9169. doi:10.1039/d3dt00213f. ISSN 1477-9226. PMID 37341481. S2CID 258885960.
  23. ^ Ajaykamal, Tamilarasan; Sharma, Mitu; Islam, Nasreen S.; Palaniandavar, Mallayan (2021). "Rapid atmospheric carbon dioxide fixation by nickel(<scp>ii</scp>) complexes: meridionally coordinated diazepane-based 3N ligands facilitate fixation". Dalton Transactions. 50 (23): 8045–8056. doi:10.1039/d1dt00299f. ISSN 1477-9226. PMID 34018498. S2CID 235074962.
  24. ^ Balamurugan, Mani; Suresh, Eringathodi; Palaniandavar, Mallayan (2021). "μ-Oxo-bridged diiron(<scp>iii</scp>) complexes of tripodal 4N ligands as catalysts for alkane hydroxylation reaction using m-CPBA as an oxidant: substrate vs. self hydroxylation". RSC Advances. 11 (35): 21514–21526. doi:10.1039/d1ra03135j. ISSN 2046-2069. PMC 9034113. PMID 35478792.
  25. ^ Periasamy, Vaiyapuri Subbarayan; Riyasdeen, Anvarbatcha; Rajendiran, Venugopal; Palaniandavar, Mallayan; Krishnamurthy, Hanumanthappa; Alshatwi, Ali Abdullah; Akbarsha, Mohammad Abdulkader (2020-10-01). "Induction of Redox-Mediated Cell Death in ER-Positive and ER-Negative Breast Cancer Cells by a Copper(II)-Phenolate Complex: An In Vitro and In Silico Study". Molecules. 25 (19): 4504. doi:10.3390/molecules25194504. ISSN 1420-3049. PMC 7583785. PMID 33019623.
  26. ^ Sheena, Thankaraj Salammal; Dhivya, Rajakumaran; Rajiu, Venkatesan; Jeganathan, K.; Palaniandavar, Mallayan; Mathan, Ganesan; Akbarsha, Mohammad Abdulkader (September 2020). "Folate-engineered mesoporous silica-encapsulated copper (II) complex [Cu(L)(dppz)]+: An active targeting cell-specific platform for breast cancer therapy". Inorganica Chimica Acta. 510: 119783. doi:10.1016/j.ica.2020.119783. ISSN 0020-1693. S2CID 219496592.
  27. ^ Sankaralingam, Muniyandi; Balamurugan, Mani; Palaniandavar, Mallayan (January 2020). "Alkane and alkene oxidation reactions catalyzed by nickel(II) complexes: Effect of ligand factors". Coordination Chemistry Reviews. 403: 213085. doi:10.1016/j.ccr.2019.213085. ISSN 0010-8545. S2CID 209706034.
  28. ^ Sharma, Mitu; Ganeshpandian, Mani; Sanjeev, Airy; Tamilarasan, Ajaykamal; Mattaparthi, Venkata Satish Kumar; Islam, Nashreen S.; Palaniandavar, Mallayan (May 2020). "Bis- and mixed-ligand copper(II) complexes of nalidixic acid the antibacterial drug: Mode of nalidixate coordination determines DNA binding and cleavage and cytotoxicity". Inorganica Chimica Acta. 504: 119450. doi:10.1016/j.ica.2020.119450. ISSN 0020-1693. S2CID 213838831.
  29. ^ Sohtun, Winaki P.; Khamrang, Themmila; Kannan, Arunachalam; Balakrishnan, Gowdhami; Saravanan, Dhandayutham; Akhbarsha, Mohammad Abdulkader; Velusamy, Marappan; Palaniandavar, Mallayan (2020-03-04). "Iron(III) bis-complexes of Schiff bases of S-methyldithiocarbazates: Synthesis, structure, spectral and redox properties and cytotoxicity". Applied Organometallic Chemistry. 34 (5). doi:10.1002/aoc.5593. ISSN 0268-2605. S2CID 216176932.
  30. ^ Sharma, Mitu; Ganeshpandian, Mani; Majumder, Munmi; Tamilarasan, Ajaykamal; Sharma, Mukesh; Mukhopadhyay, Rupak; Islam, Nashreen S.; Palaniandavar, Mallayan (2020). "Octahedral copper(<scp>ii</scp>)-diimine complexes of triethylenetetramine: effect of stereochemical fluxionality and ligand hydrophobicity on CuII/CuIredox, DNA binding and cleavage, cytotoxicity and apoptosis-inducing ability". Dalton Transactions. 49 (24): 8282–8297. doi:10.1039/d0dt00928h. ISSN 1477-9226. PMID 32510543.


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